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4hv.org :: Forums :: Chemistry
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Graphene and bromine

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Conundrum
Fri Oct 12 2018, 08:03AM Print
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Hi all.
I might have found something interesting.

A little while back some researchers invented a way to make graphene a better conductor using bromine gas.
also relevant: Link2

Seems that there might be a way to use a bromine *salt* instead in aqueous solution.
If so then it would be a very efffective way to make this compound and obviously upon removal it would retain its properties.
Wonder if anyone else has tried this?
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ShieldExperiments
Tue Oct 23 2018, 06:22PM
ShieldExperiments Registered Member #61689 Joined: Mon Jul 10 2017, 02:46PM
Location:
Posts: 14
Well, it makes sense that doping it with a bromide would make it a better conductor. At the scale of Graphene it seems that the salt would act almost like it is in solution when applied to the Graphene.
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Conundrum
Sat Feb 02 2019, 09:50AM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Yup. It appears that any halogen works but bromine is better.
(hint: I have a source but it is - problematical. )
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Sulaiman
Sat Feb 02 2019, 11:37AM
Sulaiman Registered Member #162 Joined: Mon Feb 13 2006, 10:25AM
Location: United Kingdom
Posts: 3140
Liquid or gaseous bromine is not 'friendly' to work with,
potassium bromide is available via eBay but I doubt there would be any reaction,
potassium bromate is also available and it is a fairly strong oxidiser so may work on its own,
but bromide plus bromate at low pH will release bromine, so may be useful ?
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Proud Mary
Wed Feb 06 2019, 11:43PM
Proud Mary Registered Member #543 Joined: Tue Feb 20 2007, 04:26PM
Location: UK
Posts: 4992
Sulaiman wrote ...

Liquid or gaseous bromine is not 'friendly' to work with,
potassium bromide is available via eBay but I doubt there would be any reaction,
potassium bromate is also available and it is a fairly strong oxidiser so may work on its own,
but bromide plus bromate at low pH will release bromine, so may be useful ?


Link2
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Conundrum
Fri Aug 30 2019, 05:44AM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Worth a try, thanks.
Incidentally I might have found a way to enable "hyperconductivity", not RTSC but very close. Looks like some very simple chemistry can enable a material that contains no silver yet is more conductive than it in the bulk.
In this case it uses quantum effects to increase conductance, at the cost of making the resulting material brittle.
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